溴碘甲烷 | |
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IUPAC名 Bromoiodomethane | |
识别 | |
CAS号 | 557-68-6 |
PubChem | 68407 |
ChemSpider | 61690 |
SMILES |
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InChI |
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性质 | |
化学式 | CH2BrI |
摩尔质量 | 220.84 g/mol g·mol⁻¹ |
外观 | 液体 |
密度 | 2.926 g/cm3(17 °C) |
熔点 | 1 °C |
沸点 | 139.5 °C |
危险性 | |
警示术语 | R:R37/38 R41 |
安全术语 | S:S26 S36/39 |
欧盟分类 | 刺激性 (Xi) |
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。 |
它的临界点为367.85 °C和6.3 MPa,折射率为1.6382 (20 °C, D)。
参考文献
- Tarnovsky A. N., Wall M., Gustafsson M., Lascoux N., Sundström V., Åkesson E. Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation. J. Phys. Chem. A. 2002-03, 106 (25): 5999–6005(7) [2007-06-29]. doi:10.1021/jp014306j.
- Liu Y.-J., Ajitha D., Krogh J. W., Tarnovsky A. N., Lindh R. Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane. ChemPhysChem. 2005-12, 7 (4): 955–963(9) [2007-06-29]. PMID 16596616. doi:10.1002/cphc.200500654.[永久失效链接]
- Zheng, X.; Phillips, D. L. Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct. J. Chem. Phys. 2000-08, 113 (8): 3194–3203(10). Bibcode:2000JChPh.113.3194Z. doi:10.1063/1.1286920.
- Liu K., Zhao H., Wang C., Zhang A., Ma S., Li Z. A theoretical study of bond selective photochemistry in CH2BrI. J. Chem. Phys. 2005-01, 122 (4): 044310 [2007-06-29]. PMID 15740251. doi:10.1063/1.1835955.